DOI: https://doi.org/10.32515/2414-3820.2020.50.188-195
Influence of Composition of Charge Materials of Flux-cored Wires on Mechanical Characteristics and Corrosion Resistance of Electric Arc Coatings
About the Authors
Mykhajlo Student, Senior Researcher, Professor, Doctor in Technics (Doctor of Technics Sciences), Karpenko Physico-Mechanical Institute of NAS of Ukraine, Lviv, Ukraine, e-mail: student.phmi@gmail.com, ORCID ID: 0000-0002-5992-5898
Myroslav Golovchuk, post-graduate, Karpenko Physico-Mechanical Institute of NAS of Ukraine, Lviv, Ukraine, e-mail: golovchuk86@gmail.com
Volodymyr Hvozdetskii , Senior Researcher, PhD in Technics (Candidate of Technics Sciences), Karpenko Physico-Mechanical Institute of NAS of Ukraine, Lviv, Ukraine, e-mail: gvosdetcki@gmail.com
Halyna Veselivska, Senior Researcher, PhD in Technics (Candidate of Technics Sciences), Karpenko Physico-Mechanical Institute of NAS of Ukraine, Lviv, Ukraine, e-mail: fminanu1978@gmail.com
Sergiy Markovych, Associate Professor, PhD in Technics (Candidate of Technics Sciences), Central Ukrainian National Technical University, Kropyvnytskyi, Ukraine, e-mail: marko60@ukr.net, ORCID ID: 0000-0003-1393-2360
Rostyslav Yatsyuk, Associate Professor, PhD in Technics (Candidate of Technics Sciences), Lviv Polytechnic National University, Lviv, Ukraine
Abstract
The influence of charge materials of flux-cored wires on their mechanical characteristics, chemical microheterogeneity and corrosion resistance in an aqueous solution of 3% NaCl was established. It is shown that, in contrast to coatings made of solid wires, coatings sprayed using flux-cored wires (PO) have a high chemical heterogeneity. This is due to the fact that the droplets that disperse from the PD melt and form a coating have different chemical compositions. This is caused by incomplete fusion of the charge and steel shell at the ends of the PD during electric arc spraying of coatings. To reduce the chemical micro-heterogeneity, it is proposed to add powders of ferroalloys FeSi, FeMn and self-flux PG-10H-01 to the charge of powder wire containing chromium, boron, carbon-containing components (Cr, FH, PG-100, B4C, FCB) between the components of the charge, homogenize the melt of PD and, as a consequence, reduce the microheterogeneity of the coatings. The presence of chromium, ferrochrome, ferro-silicon and ferromanganese in the charge of PD 90Х17РГС and PD 75Х19Р3ГС2 determines the minimum chemical microheterogeneity of coatings from these wires and, as a result, ensures their high corrosion resistance, which is close to corrosion steel18.
To increase the completeness of fusion of the components of the PD charge between itself and its steel shell, it is proposed to add to the PD charge powders of ferroalloys Fe-Mn, Fe-Si, which have a low melting point, able to interact with refractory components of the charge to form low-temperature eutectics.
The addition of ferro-silicon, ferromanganese and self-flux alloy PN-10H-01 powders based on ferrochrobor and ferrochrome provided high hardness of electric arc coatings, low heterogeneity in terms of chromium content in coating lamellae and, as a consequence, high corrosion resistance.
Keywords
coating, flux-cored wires, micro heterogeneity, microhardness, corrosion resistance
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References
1. Student, M.M., Pokhmurs’ka, H.V., Hvozdets’kyi, V.V., Holovchuk, M. Ya. & Romaniv, M.S. (2009). Effect of high-temperature corrosion on the gas-abrasive resistance of electric-arc coatings. Materials Science. Vol.44, 4, 481-489 [in English].
2. Pokhmurs’ka, H.V., Holovchuk, M.Ya., Dz’oba, Yu. V., Hvozdets’kyi, V.М. & Dzyubyk L.V. (2018). Influence of the composition of charge of powder wires on the structure and properties of electric-arc coatings. Materials Science, Vol.53, 6, 868-874 [in English].
3. Student, M.M., Holovchuk, M.Ya. & Hvozdets'kyj, V.M. (2017). Vplyv khimichnoho skladu poroshkovykh drotiv na strukturu ta znosostijkist' pokryttiv riznoho khimichnoho skladu [Influence of chemical composition of flux-cored wires on the structure and wear resistance of coatings of different chemical composition]. Problemy trybolohii – Problems of tribology, 3, 56-61 [in Ukrainian].
4. Korobov Yury (2018). Arc-Sprayed Fe-Based Coatings from Cored Wires for Wear and Corrosion Protection in Power Engineering. Coatings, 8(2), 71 [in English].
5. Borisova, A.L. et al. (1991). Struktura i svojstva jelektrodugovyh pokrytij na osnove ferobora, poluchennyh iz poroshkovyh provolok [Structure and properties of ferroboron-based electric arc coatings obtained from flux-cored wires]. Avtomaticheskaja svarka – Automatic welding, 9, 66 – 68 [in Russian].
6. Dallaire, S. & Levert, H. (1992). Synthesis and deposition of TiB2 containing materials by arc spraying. Surface and Coatings Technology, 50, 2, 241 – 248 [in English].
7. Student, M.M., Pokhmurs'ka, H.V., Hvozdets'kyj, V.M., Stupnyts'kyj, T.R., Posuvajlo, V.M. & Markovych, S.I. (2018). Bahatofunktsional'ni elektroduhovi pokryttia [Multifunctional electric arc coatings]. Vydavnytstvo “Prostir-M” [in Ukrainian].
8. Ana Arizmendi-Morquecho, Araceli Campa-Castilla, C. Leyva-Porras, Josué Almicar Aguilar Martinez, Gregorio Vargas Gutiérrez, Karla Judith Moreno Bello, L. López López (2014). Microstructural Characterization and Wear Properties of Fe-Based Amorphous-Crystalline Coating Deposited by Twin Wire Arc Spraying. Advances in Materials Science and Engineering, Vol. 2014. |Article ID 836739 https://doi.org/10.1155/2014/836739 [in English].
Citations
- Effect of high-temperature corrosion on the gas-abrasive resistance of electric-arc coatings / M. M. Student, H. V. Pokhmurs’ka, V. V. Hvozdets’kyi, M. Ya. Holovchuk, M. S. Romaniv. Materials Science. 2009. Vol.44, №4. Р. 481-489.
- Influence of the composition of charge of powder wires on the structure and properties of electric-arc coatings / H. V. Pokhmurs’ka, M. Ya. Holovchuk, Yu. V. Dz’oba, V. М. Hvozdets’kyi, L. V. Dzyubyk. Materials Science. 2018. Vol.53, №6. Р. 868-874.
- М. М. Студент, М. Я. Головчук, В. М. Гвоздецький. Вплив хімічного складу порошкових дротів на структуру та зносостійкість покриттів різного хімічного складу . Проблеми трибології. 2017. №3. С. 56-61.
- Korobov Yury. Arc-Sprayed Fe-Based Coatings from Cored Wires for Wear and Corrosion Protection in Power Engineering Coatings. 2018. Vol. 8(2), 71.
- Структура и свойства электродуговых покрытий на основе феробора, полученных из порошковых проволок / А. Л. Борисова, И. В. Миц, Т. В. Кайда [и др.]. Автоматическая сварка. 1991. 9. С. 66 – 68.
- Dallaire S., Levert H. Synthesis and deposition of TiB2 containing materials by arc spraying. Surface and Coatings Technology. 1992. 50, 2, P. 241 – 248.
- Багатофункціональні електродугові покриття / М.М. Студент та ін.; Фізико-механічний інститут ім. Г. В. Карпенка НАНУ, Видавництво “Простір-М”, 350. С. 2018.
- Microstructural Characterization and Wear Properties of Fe-Based Amorphous-Crystalline Coating Deposited by Twin Wire Arc Spraying / Ana Arizmendi-Morquecho, Araceli Campa-Castilla, C. Leyva-Porras, Josué Almicar Aguilar Martinez, Gregorio Vargas Gutiérrez, Karla Judith Moreno Bello, L. López López. Advances in Materials Science and Engineering. 2014, Vol. 2014. |Article ID 836739 https://doi.org/10.1155/2014/836739
Copyright (c) 2020 Mykhajlo Student, Myroslav Golovchuk, Volodymyr Hvozdetskii, Halyna Veselivska, Sergiy Markovych, Rostyslav Yatsyuk
Influence of Composition of Charge Materials of Flux-cored Wires on Mechanical Characteristics and Corrosion Resistance of Electric Arc Coatings
About the Authors
Mykhajlo Student, Senior Researcher, Professor, Doctor in Technics (Doctor of Technics Sciences), Karpenko Physico-Mechanical Institute of NAS of Ukraine, Lviv, Ukraine, e-mail: student.phmi@gmail.com, ORCID ID: 0000-0002-5992-5898
Myroslav Golovchuk, post-graduate, Karpenko Physico-Mechanical Institute of NAS of Ukraine, Lviv, Ukraine, e-mail: golovchuk86@gmail.com
Volodymyr Hvozdetskii , Senior Researcher, PhD in Technics (Candidate of Technics Sciences), Karpenko Physico-Mechanical Institute of NAS of Ukraine, Lviv, Ukraine, e-mail: gvosdetcki@gmail.com
Halyna Veselivska, Senior Researcher, PhD in Technics (Candidate of Technics Sciences), Karpenko Physico-Mechanical Institute of NAS of Ukraine, Lviv, Ukraine, e-mail: fminanu1978@gmail.com
Sergiy Markovych, Associate Professor, PhD in Technics (Candidate of Technics Sciences), Central Ukrainian National Technical University, Kropyvnytskyi, Ukraine, e-mail: marko60@ukr.net, ORCID ID: 0000-0003-1393-2360
Rostyslav Yatsyuk, Associate Professor, PhD in Technics (Candidate of Technics Sciences), Lviv Polytechnic National University, Lviv, Ukraine
Abstract
Keywords
Full Text:
PDFReferences
1. Student, M.M., Pokhmurs’ka, H.V., Hvozdets’kyi, V.V., Holovchuk, M. Ya. & Romaniv, M.S. (2009). Effect of high-temperature corrosion on the gas-abrasive resistance of electric-arc coatings. Materials Science. Vol.44, 4, 481-489 [in English].
2. Pokhmurs’ka, H.V., Holovchuk, M.Ya., Dz’oba, Yu. V., Hvozdets’kyi, V.М. & Dzyubyk L.V. (2018). Influence of the composition of charge of powder wires on the structure and properties of electric-arc coatings. Materials Science, Vol.53, 6, 868-874 [in English].
3. Student, M.M., Holovchuk, M.Ya. & Hvozdets'kyj, V.M. (2017). Vplyv khimichnoho skladu poroshkovykh drotiv na strukturu ta znosostijkist' pokryttiv riznoho khimichnoho skladu [Influence of chemical composition of flux-cored wires on the structure and wear resistance of coatings of different chemical composition]. Problemy trybolohii – Problems of tribology, 3, 56-61 [in Ukrainian].
4. Korobov Yury (2018). Arc-Sprayed Fe-Based Coatings from Cored Wires for Wear and Corrosion Protection in Power Engineering. Coatings, 8(2), 71 [in English].
5. Borisova, A.L. et al. (1991). Struktura i svojstva jelektrodugovyh pokrytij na osnove ferobora, poluchennyh iz poroshkovyh provolok [Structure and properties of ferroboron-based electric arc coatings obtained from flux-cored wires]. Avtomaticheskaja svarka – Automatic welding, 9, 66 – 68 [in Russian].
6. Dallaire, S. & Levert, H. (1992). Synthesis and deposition of TiB2 containing materials by arc spraying. Surface and Coatings Technology, 50, 2, 241 – 248 [in English].
7. Student, M.M., Pokhmurs'ka, H.V., Hvozdets'kyj, V.M., Stupnyts'kyj, T.R., Posuvajlo, V.M. & Markovych, S.I. (2018). Bahatofunktsional'ni elektroduhovi pokryttia [Multifunctional electric arc coatings]. Vydavnytstvo “Prostir-M” [in Ukrainian].
8. Ana Arizmendi-Morquecho, Araceli Campa-Castilla, C. Leyva-Porras, Josué Almicar Aguilar Martinez, Gregorio Vargas Gutiérrez, Karla Judith Moreno Bello, L. López López (2014). Microstructural Characterization and Wear Properties of Fe-Based Amorphous-Crystalline Coating Deposited by Twin Wire Arc Spraying. Advances in Materials Science and Engineering, Vol. 2014. |Article ID 836739 https://doi.org/10.1155/2014/836739 [in English].
Citations
- Effect of high-temperature corrosion on the gas-abrasive resistance of electric-arc coatings / M. M. Student, H. V. Pokhmurs’ka, V. V. Hvozdets’kyi, M. Ya. Holovchuk, M. S. Romaniv. Materials Science. 2009. Vol.44, №4. Р. 481-489.
- Influence of the composition of charge of powder wires on the structure and properties of electric-arc coatings / H. V. Pokhmurs’ka, M. Ya. Holovchuk, Yu. V. Dz’oba, V. М. Hvozdets’kyi, L. V. Dzyubyk. Materials Science. 2018. Vol.53, №6. Р. 868-874.
- М. М. Студент, М. Я. Головчук, В. М. Гвоздецький. Вплив хімічного складу порошкових дротів на структуру та зносостійкість покриттів різного хімічного складу . Проблеми трибології. 2017. №3. С. 56-61.
- Korobov Yury. Arc-Sprayed Fe-Based Coatings from Cored Wires for Wear and Corrosion Protection in Power Engineering Coatings. 2018. Vol. 8(2), 71.
- Структура и свойства электродуговых покрытий на основе феробора, полученных из порошковых проволок / А. Л. Борисова, И. В. Миц, Т. В. Кайда [и др.]. Автоматическая сварка. 1991. 9. С. 66 – 68.
- Dallaire S., Levert H. Synthesis and deposition of TiB2 containing materials by arc spraying. Surface and Coatings Technology. 1992. 50, 2, P. 241 – 248.
- Багатофункціональні електродугові покриття / М.М. Студент та ін.; Фізико-механічний інститут ім. Г. В. Карпенка НАНУ, Видавництво “Простір-М”, 350. С. 2018.
- Microstructural Characterization and Wear Properties of Fe-Based Amorphous-Crystalline Coating Deposited by Twin Wire Arc Spraying / Ana Arizmendi-Morquecho, Araceli Campa-Castilla, C. Leyva-Porras, Josué Almicar Aguilar Martinez, Gregorio Vargas Gutiérrez, Karla Judith Moreno Bello, L. López López. Advances in Materials Science and Engineering. 2014, Vol. 2014. |Article ID 836739 https://doi.org/10.1155/2014/836739